microwave assisted oxidation coupling of thiols to symmetrical disulfides with tripropylammonium fluorochromate (vi) (tpafc)

نویسندگان

mohammad kazem mohammadi

islamic azad university, ahvaz branch , faculty of science, ahvaz , iran neda hasanzadeh

islamic azad university, ahvaz branch , faculty of science, ahvaz , iran shahriare ghammamy

department of chemistry, faculty of science, imam khomeini international university, qazvin, iran

چکیده

tripropylammonium fluorochromate(vi) (tpafc), is an efficient and new reagent, which isprepared easily and oxidizes thiols to the corresponding disulfides, quickly. the reactions areperformed cleanly and are controlled to stop at the disulfide stage, without over-oxidation andside products. coupling of thiols to their corresponding disulfides, are studied in solution atroom temperature and in solution under microwave radiation. the easy procedure, simple workup,short reaction times, and excellent yields, are another advantages of this reagent.

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منابع مشابه

Microwave assisted oxidation coupling of thiols to symmetrical disulfides with tripropylammonium fluorochromate (VI) (TPAFC)

Tripropylammonium fluorochromate(VI) (TPAFC), is an efficient and new reagent, which isprepared easily and oxidizes thiols to the corresponding disulfides, quickly. The reactions areperformed cleanly and are controlled to stop at the disulfide stage, without over-oxidation andside products. Coupling of thiols to their corresponding disulfides, are studied in solution atroom temperature and in s...

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عنوان ژورنال:
journal of the iranian chemical research

جلد ۳، شماره ۳، صفحات ۱۵۵-۱۶۰

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